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PROCESS FOR EPOXYDATION OF OLEFINIC COMPOUNDS WITH HYDROGEN PEROXIDECM Patents

PCT No. PCT/ES98/00078 Sec. 371 Date Feb. 16, 2000 Sec. 102(e) Date Feb. 16, 2000 PCT Filed Mar. 26, 1998 PCT Pub. No. WO99/48884 PCT Pub. Date Sep. 30, 1999Epoxidation procedure for olefinic compounds with hydrogen peroxide in the presence of solvents, preferably C1-C8 alcohols, using silica supported titanium catalysts, prepared by the impregnation of the silica with solutions of titanium alkoxydes and/or titanocenes in oxygenated organic solvents.

Datos clave

CategoríaInvención

Índice de la ficha

Updated at
05/11/2026
Numero publicacion
EP.0987259.A1
Fecha publicacion
22/03/2000
Anio publicacion
2000

En detalle

Reivindicaciones

1. Liquid phase epoxidation procedure in the liquid phase of carbon-carbon double bonds of olefinic compounds with hydrogen peroxide in the presence of solvents, at temperatures ranging between approximately 50° and 140°C, characterised in that the use of silica supported titanium catalyst, in which said catalysts are prepared by the impregnation of silicas with a specific surface ranging between 50 and 900 m<2>/g with solutions of titanium alkoxydes and/or titanocenes in oxygenated organic solvents, followed by the separation of the excess solution and of the solvent. 2. Procedure according to claim 1 characterised in that the oxygenated organic solvent is a C<1>-C<8> alcohol. 3. Procedure according to claims 1 and 2 characterised in that the catalyst is added, by means of impregnation, with alkaline or alkaline-earth metals salts in amounts ranging between approximately 0.01 and 0.1% in weight (weight of alkaline or alkaline-earth metals per 100 g of catalyst). 4. Procedure according to claims 1 through 3 characterised in that it uses hydrogen peroxide solutions in organic solvents with concentrations ranging between approximately 1 and 15% in weight. 5. Procedure according to claim 4 characterised in that it uses hydrogen peroxide solutions obtained by means of the oxidation of secondary alcohols with molecular oxygen or air. 6. Procedure according to claims 1 through 5 characterised in that the olefinic compound is an alkene or a cycloalkene. 7. Procedure according to claim 6 characterised in that the alkene is propylene. 8. Procedure according to claim 6 characterised in that the cycloalkene is cyclohexene. 9. Procedure according to claim 6 characterised in that the olefinic compound is an allylic alcohol. 10. Procedure according to claim 6 characterised in that the olefinic compound is fumaric acid or maleic acid or one of its esters, anhydrides or mixtures thereof. 11. Procedure according to claims 1 through 10 characterised in that C<6>-C<9> aromatic alcohols or C<1>-C<6> aliphatic alcohols are used in the epoxidation reaction as solvents. 12. Procedure according to claim 11 characterised in that the organic solvent is 2-methyl-2-propanol or mixtures of organic solvents containing 2-methyl-2-propanol.

Etiquetas

Inventores
De Frutos Escrig, PilarDe Frutos Escrig PilarCampos Martin Jose MiguelCampos Martin, Jose Miguel데프루토스에스크리그,필라캄포스마틴,호세미구엘Escrig Pilar de FrutosPilar de Frutos EscrigMartin Jose Miguel CamposJose Miguel Campos MartinEscrigPilar de FrutosMartin Josemiguel CamposMartinJosemiguel Campos
Solicitantes
Repsol Química S.A.
Clasificacion ipc
B01J 21/ 06 A IC07D 301/ 12 A IC07D 303/ 04 A I
Clasificacion cpc
4C048/AA014C048/AA044C048/AA054C048/BB014C048/BB024C048/BB074C048/BB314C048/BC014C048/CC014C048/UU034C048/XX024G069/AA034G069/AA084G069/BA02A4G069/BA02B4G069/BA21C4G069/BA27C4G069/BB04B4G069/BC01A4G069/BC06C4G069/BC08A4G069/BC50A4G069/BC50B4G069/BC50C4G069/BE04C4G069/CB074G069/CB094G069/CB734G069/DA034G069/DA064G069/EA02Y4G069/EC02X4G069/EC03X4G069/EC03Y4G069/EC04X4G069/EC08Y4G069/FA024G069/FB144G069/FB294G069/FB304G069/FC104G169/AA034G169/AA084G169/BA02A4G169/BA02B4G169/BA21C4G169/BA27C4G169/BB04B4G169/BC01A4G169/BC06C4G169/BC08A4G169/BC50A4G169/BC50B4G169/BC50C4G169/BE04C4G169/CB074G169/CB094G169/CB734G169/DA034G169/DA064G169/EA02Y4G169/EC02X4G169/EC03X4G169/EC03Y4G169/EC04X4G169/EC08Y4G169/FA024G169/FB144G169/FB294G169/FB304G169/FC10B01J21/06&ZC07D301/12C07D303/04549/531
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