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Process for producing hydrogenated rubbersCM Patents

PROBLEM TO BE SOLVED: To provide a process for producing a hydrogenated polymer that makes easy and effective deactivation of a living polymer before the hydrogenation step possible and that has good characteristics, by producing a conjugated diene polymer or copolymer by solution polymerization in the presence of an alkyllithium, adding a specified deactivating compound to it, adding a hydrogenation catalyst to the mixture and keeping the resulting mixture under pressure of hydrogen. SOLUTION: The conjugated diene polymer or copolymer has an average molecular weight of 500-1,000,000 and is desirably a copolymer of a conjugated diene such as 1,3-butadiene with a vinylaromatic compound such as styrene. The deactivating compound used is selected among R-OH, R-COOH, R'n -SiCl4-n and R'n -Sn-Cl4-n . In the formulae, n=0-3; R is a 2-20C alkyl having a polar group; and R' is a 1-20C alkyl or a 6-20C aryl. It is desirably ethylene glycol or 2-methyl-2,4-pentanediol. It is used in an amount equivalent to that of the polymerization catalyst used.

Datos clave

CategoríaInvención

Índice de la ficha

Updated at
05/11/2026
Numero publicacion
EP.0885905.A1
Fecha publicacion
23/12/1998
Anio publicacion
1998

En detalle

Reivindicaciones

1. Process for producing a hydrogenated rubber comprising the following steps: A. polymerization in solution of one or more monomers in the presence of a lithium alkyl to produce polymers or copolymers of conjugated dienes. B. addition to the reaction mixture of a compound selected from the following classes: R-OH, R-COOH, R'<n>-Si-Cl <4-n> , R'<n>-Sn-Cl<4-n> with n comprised between 0 and 3, extremes included, in an amount of equivalents which is at least equal to the amount of polymerization catalyst, wherein R is a C<2>-C<20> alkyl group optionally containing one or more polar functional groups selected from C-OH, COOH and such that the compound has a solubility in water / solubility in hydogenation solvent ratio higher than 49 and/or boiling point higher than 110°C; R' is a C<1>-C<20> alkyl or C<6>-C<20> aryl. C. hydrogenation of the deactivated polymer by adding to the mixture a hydrogenation catalyst and maintaining the mixture under hydrogen pressure, in a continuous, semicontinuous or batch manner, using stirred, tubular or loop reactors. 2. The process according to claim 1, wherein in step b) the deactivating compound is selected from ethylene glycol and 2-methyl-2,4-pentanediol. 3. The process according to claim 1 or 2 wherein in step a) copolymers of a conjugated diene such as 1,3-butadiene or isoprene, with vinylaromatic compounds such as styrene and a-methylstyrene are prepared. 4. The process according to claim 3 wherein in step a) a butadiene-styrene block copolymer is prepared. 5. The process according to claims 1-4 wherein the average molecular weight of the polymer is from 500 to 1000000. 6. The process according to claims 1-5 wherein in step c) the catalyst used is a titanocene compound, optionally in the presence of a cocatalyst. 7. The process according to claim 5 wherein the catalyst used is selected from Cp<2>Ti(PhOR)<2> and Cp<2>Ti(CH<2>PPh<2>)<2>.

Etiquetas

Inventores
Parellada Ferrer Maria DoloresFerrer Maria Dolores ParelladaCalle Juan Antonio BarrioBarrio Calle Juan AntonioEspinosa Soriano Maria JoseSoriano Maria Jose EspinosaJ��A��B������Ferrer Dolores Parellada���ﰢ��Soriano Jose EspinosaBarrio Calle, Juan AntonioParellada Ferrer, Maria DoloresEspinosa Soriano, Maria JoseJuan Antonio Barrio CarreMa Dolores Palerada FerrerMa Hose Espinosa SolianoCalleJuan Antonio BarrioFerrerMaria Dolores ParelladaSorianoMaria Jose Espinosa
Solicitantes
Repsol Química S.A.����������Ѧ�ɷݹ�˾
Clasificacion ipc
C08C 19/ 02 A IC08F 2/ 04 A IC08F 297/ 04 A IC08F 36/ 04 A IC08F 4/ 48 A IC08F 6/ 02 A IC08F 8/ 04 A I
Clasificacion cpc
4J011/HA064J011/HB224J011/NA194J011/NA204J011/NA284J011/NA294J015/DA024J026/HA064J026/HA264J026/HA324J026/HA394J026/HB154J026/HB164J026/HB494J026/HB504J026/HC064J026/HC484J026/HC494J026/HE024J026/HE054J100/AB02Q4J100/AB03Q4J100/AS02P4J100/AS03P4J100/CA044J100/CA314J100/DA014J100/FA084J100/FA194J100/GA054J100/GA064J100/GA084J100/HA044J100/HB024J100/HC834J100/HE41C08C19/02C08F2/04C08F297/04C08F36/04C08F4/48C08F6/02525/314525/332.3525/332.9525/333.1525/333.2525/338525/52
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