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Chromium catalysts active in olefin polymerisationCM Patents

[0001] The present invention relates to chromium (III) complexes of formula I <img class="EMIRef" id="449869954-ia01" /> and to olefin polymerisation catalysts comprising a chromium (III) complex of formula I and one or more activators.

Datos clave

CategoríaInvención

Índice de la ficha

Updated at
05/11/2026
Numero publicacion
EP.1325924.A1
Fecha publicacion
09/07/2003
Anio publicacion
2003
Numero solicitud
EP20020380001

En detalle

Reivindicaciones

1. A chromium (III) tridentate complex of formula I <img class="EMIRef" id="449869956-ib0048" /> wherein: Z is a group comprising at least a nitrogen, phosphorous, oxygen or sulfur atom which is able to coordinate to the chromium atom; each R<1> is independently selected from the group consisting of H and a monovalent radical comprising from 1 to 30 carbon atoms and from 0 to 5 heteroatoms independently selected from Si, N, P, O, F, Cl and B atoms; each R<2> is independently selected from the group consisting of H and a monovalent radical comprising from 1 to 30 carbon atoms and from 0 to 5 heteroatoms independently selected from Si, N, P, O, F, Cl and B atoms; each R<2> can join together with either R<1> or Z forming one or more aromatic or aliphatic rings optionally containing heteroatoms; each A is independently selected from nitrogen, phosphorous, As and Sb; each E is independently selected from carbon, phosphorus and nitrogen; each p is independently 1 or 2; each n is independently 0, 1 or 2; and each X is independently an atom or group covalently or ionically attached to the chromium atom. 2. Chromium complex according to claim 1, wherein Z is selected from the group consisting of: <img class="EMIRef" id="449869956-ib0049" /> <img class="EMIRef" id="449869956-ib0050" /> wherein each R<3> is independently selected from linear or branched C<1> -C<20> alkyl, C<6> -C<30> aryl, hydroxyl, amino, nitro, tri(linear or branched C<1> -C<20> alkyl)silyl, linear or branched C<1> -C<20> alkoxy, chlorine, bromine, fluorine and trifluoromethyl; m is 0, 1, 2 or 3; A is nitrogen; and E is carbon. 3. Chromium complex according to anyone of claims 1 or 2, wherein each R<1> is independently s phenyl radical optionally substituted in the positions 2 and/or 6. 4. Chromium complexes according to anyone of claims 1 or 2, wherein each R<2> is independently selected from hydrogen, linear or branched C<1> -C<20> alkyl, C<3> -C<20> cycloalkyl, silyl, C<6> -C<30> aryl, linear or branched C<2> -C<20> alkenyl, optionally comprising 1 to 5 heteroatoms independently selected from Si, N, P, O, F, Cl and B atoms. 5. An olefin polymerisation catalyst comprising a chromium complex according to anyone of claims 1 to 4 and one or more activators. 6. Olefin polymerisation catalyst according to claim 5, further comprising an inorganic or organic support. 7. Olefin polymerisation catalysts according to anyone of claims 5 or 6, further comprising a Ziegler-Natta catalyst. 8. Olefin polymerisation catalyst according to anyone of claims 5 or 6, further comprising a metallocene catalyst. 9. A process for the (co)polymerisation of alpha olefins characterized by the use of a catalyst system according to anyone of claims 5 to 8. 10. Process according to claim 9, wherein the olefin used is ethylene optionally in combination with a C<3> -C<8> alpha olefin.

Etiquetas

Inventores
Mendez Llatas LuisMendez Llatas, LuisSanz Gil EncarnaSanz Gil, EncarnaSancho Royo, JoseSancho Royo JoseEsteruelas Rodrigo Miguel AngeEsteruelas Rodrigo, Miguel AngelLopez de Lama Ana MargaritaLopez de Lama, Ana MargaritaOlivan Esco MontserratOlivan Esco, MontserratOnate Rodriguez EnriqueOnate Rodriguez, Enrique
Solicitantes
Repsol Química S.A.
Clasificacion ipc
C07F 11/ 00 A IC08F 10/ 02 A IC08F 110/ 02 A IC08F 4/ 69 A IC08F 10/ 06 A I
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