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OXIDE MATERIALS, PROCESS FOR THEIR PREPARATION AND CATALYST COMPOSITIONS CONTAINING THESE MATERIALSCM Patents

The present invention provides an oxide material having in its calcined form an X-ray diffraction pattern including values substantially as set forth in Table (I) and an adsorption capacity for 1,3,5-trimethylbenzene at a temperature of 42 DEG C and a pressure of 173.3 Pa (1.3 torr) of at least 0.50 mmol/g; a process for its preparation; a catalyst composition containing it; and use of the catalyst composition in a process for catalytically cracking a hydrocarbonaceous feedstock.

Datos clave

CategoríaInvención

Índice de la ficha

Updated at
05/11/2026
Numero publicacion
EP.0859742.A1
Fecha publicacion
26/08/1998
Anio publicacion
1998

En detalle

Reivindicaciones

1. A non-pillared oxide material having an adsorption capacity for 1,3,5-trimethylbenzene at a temperature of 42 °C and a pressure of 173.3 Pa (1.3 torr) of least 0.50 mmol/g, obtainable by a process which comprises, prior to calcination, at least partially delaminating a swollen layered oxide material having an X-ray diffraction pattern including values substantially as set forth in Table II below: Table II > 32.2 vs 12.41 ± 0.25 w-s 3.44 ± 0.07 w-s 2. A process for the preparation of an oxide material having an adsorption capacity for 1,3,5-trimethylbenzene at a temperature of 42 °C and a pressure of 173.3 Pa (1.3 torr) of least 0.50 mmol/g, which comprises, prior to calcination, at least partially delaminating a swollen, layered oxide material having an X-ray diffraction pattern including values substantially as set forth in Table II below: Table II > 32.2 vs 12.41 ± 0.25 w-s 3.44 ± 0.07 w-s 3. A process according to claim 2, wherein the swollen, layered oxide material is at least partially delaminated using ultrasound techniques. 4. A process according to claim 2 or claim 3, which also comprises an acid treatment step after the delamination step. 5. A process according to any one of claims 2 to 4, which also comprises a post-calcination hydrothermal treatment step. 6. A process according to any one of claims 2 to 5, which also comprises a post-calcination fluorine and/or phosphorus treatment step. 7. A catalyst composition comprising an oxide material as claimed in claim 1, and a matrix material. 8. A catalyst composition according to claim 7, wherein the matrix material is a refractory oxide. 9. A process for catalytically cracking a hydrocarbonaceous feedstock which comprises contacting the feedstock at elevated temperature with a catalyst composition according to claim 7 or claim 8.

Etiquetas

Inventores
Canos Avelino CormaAvelino Corma CanosSegui Vicente FornesVicente Fornes SeguiPergher Sibelle Berenice CasteSibelle Berenice Castella PergherCorma Canos, AvelinoCorma Canos AvelinoSegui, Vicente FornesPergher, Sibelle Berenice CastellaPergher Sibelle BereniceCorma Camos AvelinoFornes Segui VicentePergher SibelePergher Sibele B CFornes Segui, VicenteCastella Pergher Sibelle BerenCastella Pergher, Sibelle BerenicePergher Sibelle Berenice CastellaCanos, Avelino Corma
Solicitantes
Shell Int ResearchShell Internationale Research Maatschappij B.V.Universitat Politècnica de ValènciaConsejo Superior de Investigaciones CientíficasUniversidad Politecnica de Valencia Consejo Superior de Invest. Cientificas
Clasificacion ipc
B01J 29/ 04 A IC01B 33/ 38 A IC01B 39/ 48 A IC10G 11/ 05 A I
Clasificacion cpc
208/118208/119208/120.01423/328.1423/328.2502/245502/263
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