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Aromatics alkylationCM Patents

[0001] The invention provides a process for the alkylation of an aromatics compound with an olefin alkylation agent which comprises contacting the aromatic compound, especially benzene, with the alkylation agent, especially ethylene and/or propylene, in the presence of an oxide material which is delayered MWW-type zeolitic material, very suitably the material known as ITQ-2.

Datos clave

CategoríaInvención

Índice de la ficha

Updated at
05/11/2026
Numero publicacion
EP.1242343.A1
Fecha publicacion
25/09/2002
Anio publicacion
2002

En detalle

Reivindicaciones

1. A process for the alkylation of an aromatic compound with a olefin alkylation agent which comprises contacting the aromatic compound with the alkylation agent in the presence of a calcined oxide material which is a delayered MWW zeolite. 2. A process as claimed in claim 1, wherein at least 50% of the calcined oxide material comprises single layer material. 3. A process as claimed in claim 2, wherein the delayered MWW zeolite has been obtained by delamination, prior to calcination, of a swollen intermediate material or an as-synthesised material of the MWW-type structures PSH-3, SSZ-25, ERB-1, ITQ-1, or MCM-22. 4. A process as claimed in claim 3, wherein the swollen intermediate material comprises a template being hexamethyleneimine, or a source of adamantane quaternary ammonium ions, or a mixture thereof. 5. A process as claimed in any one of claims 1 to 4, wherein the delayered oxide material is characterised in its calcined form as a microporous structure of channels formed by 10-membered atomic rings having a pore diameter of 0.56 nm (5.6 Å) and chalice-shaped cavities that measure 0.8 x 0.7 nm (8 x 7 Å) which are open to the outside via 12-membered atomic rings and an adsorption capacity for 1,3,5-trimethylbenzene at a temperature of 42 °C and a pressure of 173.3 Pa of at least 0.50 mmol/g. 6. A process as claimed in any one of claims 1 to 5, wherein the aromatic compound is benzene and the olefin alkylation agent is ethylene, propylene or a mixture thereof. 7. A process as claimed in claim 6, which is carried out in liquid phase operation at a temperature in the range of from 150 to 250 °C, a pressure in the range of from 3 to 5 MPa, a benzene to olefin molar ratio in the range of from 2:1 to 10:1, and a weight hourly space velocity in the range of from 1 to 10. 8. A process as claimed in claim 7, which is carried out in a fixed bed reactor, or in a catalytic distillation reactor or reactor system. 9. A process as claimed in any one of claims 6 to 8, which is the production of cumene from propylene and benzene.

Etiquetas

Inventores
Van den Brink Peter JohnVan den Brink, Peter, JohnCorma Canos, AvelinoCorma Canos AvelinoCreyghton, Edward, JuliusCreyghton Edward JuliusFornes Segui VicenteFornes Segui, VicenteMartinez Soria VicenteMartinez Soria, VicentePeter John van den BrinkBrink Peter John van denCanos Avelino CormaAvelino Corma CanosEdward Julius CreyghtonSegui Vicente FornesVicente Fornes SeguiSoria Vicente MartinezVicente Martinez SoriaCreyghton, Edward JuliusVan den Brink, Peter JohnVan den Brink JohnVan den Brink, JohnCreyghton JuliusCreyghton, JuliusCorma Canos, Avelino IaFornes Segui, Vicente CiaMartinez Soria Vicente Uni Pol
Solicitantes
Consejo Superior de Investigaciones CientíficasUniversitat Politècnica de València
Clasificacion ipc
B01J 29/ 04 A IB01J 29/ 70 A IB01J 37/ 34 A IC01B 33/ 26 A IC07B 61/ 00 A IC07C 15/ 02 A IC07C 15/ 073 A IC07C 15/ 085 A IC07C 2/ 66 A I
Clasificacion cpc
4G069/AA024G069/AA084G069/BA07A4G069/BA07B4G069/CB624G069/DA054G069/FA014G069/FB304G069/FB584G069/ZA32B4G069/ZD104G069/ZE094G073/BA694G073/BB084G073/BB104G073/BB124G073/BB444G073/BB464G073/BB484G073/BB704G073/CZ414G073/CZ504G073/FB124G073/FB264G073/FB364G073/FC254G073/FD024G073/FD204G073/FD214G073/FD304G073/FE204G073/FF044G073/GA194G169/AA024G169/AA084G169/BA07A4G169/BA07B4G169/CB624G169/DA054G169/FA014G169/FB304G169/FB584G169/ZA32B4G169/ZD104G169/ZE094H006/AA024H006/AC214H006/AC234H006/BA644H006/BA714H006/BA814H006/BC104H006/BC114H006/BC144H006/BC184H006/BC314H006/BC404H006/DA154H006/DA464H039/CA124H039/CA194H039/CA414H039/CF10B01J29/70&ZB01J37/34C01B33/26C07B61/00&300C07C15/073C07C15/085C07C2/66585/467585/906
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